A novel 3D cyano-bridged mixed-valence CoII/CoIII canted antiferromagnet constructed from defective cubanes. Synthesis, X-ray structure and magnetic properties
Identifieur interne : 000805 ( Main/Exploration ); précédent : 000804; suivant : 000806A novel 3D cyano-bridged mixed-valence CoII/CoIII canted antiferromagnet constructed from defective cubanes. Synthesis, X-ray structure and magnetic properties
Auteurs : Antonio Rodríguez-Diéguez [Espagne] ; Raikko Kivek S [Finlande] ; Hiroshi Sakiyama [Japon] ; Ahderrahmane Debdoubi [Maroc] ; Enrique Colacio [Espagne]Source :
- Dalton Transactions [ 1477-9226 ] ; 2007.
Abstract
The hydrothermal reaction of 2-pyrimidine-carboxamide, CoCl2·6H2O and K3[Co(CN)6] affords a novel mixed-valence CoII/CoIII 3D complex K[Co3(CN)6(ox)(H2O)2]·H2O, which contains cyano-bridged Co7 defective cubanes connected by oxalate and cyanide bridging groups and behaves as a canted antiferromagnet with Tc = 17.5 K.
Url:
DOI: 10.1039/b618479k
Affiliations:
- Espagne, Finlande, Japon, Maroc
- Andalousie, Uusimaa
- Grenade (Espagne), Helsinki
- Université d'Helsinki, Université de Grenade
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